N-(2-Chloroquinolin-3-ylmethylene)aniline
نویسندگان
چکیده
The title compound, C(16)H(11)ClN(2), displays a trans configuration across the C=N bond and a transoid arrangement across the quinoline ring and the azomethine C atom. This arrangement facilitates C-H⋯Cl interactions. The packing in the crystal structure is due to inter-molecular C-H⋯π and Cl⋯π (3.52 and 3.84 Å) inter-actions. The dihedral angle between the least-squares planes of 2-chloro-quinoline and phenyl-amine is 16.61 (2)°.
منابع مشابه
Benzyl N′-(4,6-dimethoxy-2-methyl-3-phenyl-1H-indol-7-ylmethylene)hydrazinecarbodithioate
The asymmetric unit of the title compound, C(26)H(25)N(3)O(2)S(2), contains two independent mol-ecules, which are linked by a pair of N-H⋯S hydrogen bonds, forming a dimer.
متن کاملBenzyl N′-(1-methyl-1H-indol-2-ylmethylene)hydrazinecarbodithioate
In the title compound, C(18)H(17)N(3)S(2), the dihedral angle between the planes of the aromatic ring systems is 83.63 (16)°. In the crystal structure, inversion dimers occur, linked by pairs of N-H⋯S hydrogen bonds.
متن کامل(E)-N′-(Furan-2-ylmethylene)-4-(quinolin-8-yloxy)butanohydrazide
In the title mol-ecule, C(18)H(17)N(3)O(3), the dihedral angle between the mean planes of the furan ring and the quinoline group is 77.4 (2)°. In the crystal structure, inter-molecular N-H⋯N hydrogen bonds link the mol-ecules into centrosymmetric dimers.
متن کامل2-[(2-Chloroquinolin-3-yl)(hydroxy)methyl]acrylonitrile
In the title compound, C13H9ClN2O, the dihedral angle between the acrylo-nitrile C=C-CN plane and the quilonine ring system is 71.3 (2)°. In the crystal, mol-ecules are linked by O-H⋯N hydrogen bonds, forming chains along [01-1]. The chains are linked into a three-dimensional network through C-H⋯N inter-actions.
متن کاملN-(4-Methylbenzyl)-3-nitroaniline
In the title compound, C(14)H(14)N(2)O(2), the angle between the mean plane of the N-methyl-3-nitro-aniline system (r.m.s. deviation = 0.0185 Å) and the p-tolyl unit is 89.79 (4)°. In the crystal, hydrogen-bonded chains running along [10-1] are generated by the linking of neighbouring mol-ecules via N-H⋯O and C-H⋯O hydrogen bonds involving the 3-nitro-aniline systems and forming R(2) (2)(8) mot...
متن کامل